Nanophase iron carbides in fine‐grained rims in CM2 carbonaceous chondrites: Formation of organic material by Fischer–Tropsch catalysis in the solar nebula     

Adrian J. Brearley 《Meteoritics & planetary science》2021,56(1):108-126

Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites.  相似文献   

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream     

Sam J. Leuthold  Stephanie A. Ewing  Robert A. Payn  Florence R. Miller  Stephan G. Custer 《水文研究》2021,35(2):e14029

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   

The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification     

Kaizad F. Patel  Ivan J. Fernandez  Sarah J. Nelson  Stephen A. Norton  Cheryl J. Spencer 《水文研究》2021,35(5):e14147

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   

Analysis of one-dimensional models for exchange flows under strong stratification     

Kaptein  Steven J.  van de Wal  Koen J.  Kamp  Leon P. J.  Armenio  Vincenzo  Clercx  Herman J. H.  Duran-Matute  Matias 《Ocean Dynamics》2020,70(1):41-56

Ocean Dynamics - One-dimensional models of exchange flows driven by horizontal density gradients are well known for performing poorly in situations with weak turbulent mixing. The main issue with...  相似文献   

三峡工程运用后坝下游河道泥沙输移变化规律   总被引：2，自引：2，他引：0  

郭小虎  渠庚  刘亚  刘心愿 《湖泊科学》2020,32(2):564-572

三峡工程蓄水后"清水"下泄,坝下游河段将会长期处于严重不饱和状态,水流含沙量沿程恢复将会引起坝下游长距离冲刷,本文根据三峡工程蓄水前、后的实测资料分析了坝下游河道泥沙输移变化规律,探索不同粒径组沙量沿程恢复对河床冲刷的影响,得到以下结论:在蓄水初期d≤0.031 mm沙量恢复主要受河床补给与江湖入汇共同的影响,随着水库下泄该粒径组沙量递减,使得各站该粒径组年均输沙量均远小于蓄水前的水平,沙量恢复仍主要受河床补给与江湖入汇的影响,这是造成坝下游河道发生长距离冲刷的主要原因之一;在蓄水初期0.031 mmd≤0.125 mm沙量恢复主要受河床补给的影响,但江湖入汇的影响较大,随着河床补给量逐渐减少,各站该粒径组年均输沙量均小于蓄水前的水平,沙量恢复仍主要受河床补给的影响,江湖入汇的影响逐渐减小,这也是坝下游河道发生长距离冲刷的主要原因之一; d0.125 mm沙量恢复主要受河床补给的影响,蓄水初期该粒径组沙量在宜昌监利河段沿程恢复速率较快,且在监利站达到蓄水前的水平,随着时间推移,在宜昌监利河段沿程恢复且速率仍较快,在监利站达到最大值,其数值逐渐小于蓄水前的水平,这是造成坝下游河道冲刷重点集中在宜昌监利河段的主要原因.  相似文献   

Analysis of soil drying incorporating a constitutive model for curling     

Maedo  Michael  Sánchez  Marcelo  Aljeznawi  Duaa  Manzoli  Osvaldo  Guimarães  Leonardo J. N.  Cleto  Pedro Rogério 《Acta Geotechnica》2020,15(9):2619-2635

This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.

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绿色空间对休闲性体力活动影响的社区分异 ——以广州市为例     

戴颖宜  朱战强  周素红 《热带地理》2019,39(2):237-246

以广州市20个典型社区为例，构建多元线性回归模型，探讨了绿色空间对居民休闲性体力活动的影响，并剖析绿色空间对不同类型社区居民休闲性体力活动影响的作用机制。结果发现：1）不同类型社区居民的休闲性体力活动水平存在明显差异，低档社区的为782.99 MET-min/w，中档社区的为871.70 MET-min/w，高档社区的为1 227.91 MET-min/w；2）影响不同类型社区居民休闲性体力活动水平的绿色空间因素有所不同，低档社区、中档社区和高档社区的显著因子分别为“到最近公园广场距离”“邻里绿化覆盖率”和“健身活动设施数量”；3）绿色空间对休闲性体力活动水平影响的作用机制存在社区差异，低档社区居民休闲性体力活动主要受到成本作用的约束，中档社区居民主要受绿化环境作用影响，而高档社区居民主要受机会作用影响。  相似文献   

以PAC为原料合成锂吸附剂的工艺研究          下载免费PDF全文

张文丁  邓小川  朱朝梁  樊发英  张毅  樊洁  史一飞  卿彬菊 《盐湖研究》2019,27(4):55-61

研究了聚合氯化铝(PAC)为原料合成锂吸附剂的基本工艺路线,并探究了加料方式、反应物配比、反应温度、反应时间和加料速度等对所合成吸附剂吸附量的影响,研究结果表明配比是影响吸附剂吸附量的最主要因素,得到了最佳合成条件,在此条件下所合成吸附剂对锂离子的吸附容量为6.1 mg/g。推断吸附剂的主要成分为晶态或非晶态的LiCl·2Al(OH)_3·nH_2O,同时含有Al(OH)_3、(CaO)_3Al_2O_3·6H_2O及LiCl·H_2O等成分。从吸附结果来看,结晶度较差的片状LiCl·2Al(OH)_3·nH_2O和非晶态的Al(OH)_3为主成分的吸附剂吸附性能最好。  相似文献   

米氏凯伦藻细胞表面膜蛋白质组及其对温度变化的响应研究     

王坤  王沛  张浩  张树峰  王大志 《海洋与湖沼》2019,50(3):652-663

米氏凯伦藻(Karenia mikimotoi)近年在我国福建、浙江和广东沿海经常形成赤潮,其赤潮不仅影响到海洋生态系统的稳定,也严重威胁到水产养殖以及人类生命健康安全。本论文以米氏凯伦藻为研究对象,建立了米氏凯伦藻细胞表面膜蛋白质荧光标记技术和细胞膜蛋白质提取方法,运用荧光差异凝胶电泳技术(2-DDIGE)对膜蛋白质进行了分析,并研究了米氏凯伦藻的膜蛋白质组及其对环境温度变动的响应。实验共鉴定到44个细胞表面膜蛋白,其中有效注释27个,主要为转运蛋白、HSP70蛋白家族和捕光蛋白等。米氏凯伦藻在20°C条件下的细胞生长和光合作用要明显好于16°C和12°C,但16°C和12°C条件下的差别不大,表明低温限制了米氏凯伦藻的生长。当米氏凯伦藻从12°C快速转移至16°C和20°C时,藻细胞密度和光合作用效率短时间迅速降低,但细胞很快即适应温度变化。细胞膜上的转运蛋白和光合作用蛋白在其适应温度变化中起着重要作用。  相似文献   

长江河口潮波传播机制及阈值效应分析   总被引：1，自引：0，他引：1  

张先毅  黄竞争  杨昊  欧素英  刘锋  蔡华阳  杨清书 《海洋与湖沼》2019,50(4):788-798

河口潮波传播过程受沿程地形(如河宽辐聚、水深变化)及上游径流等诸多因素影响,时空变化复杂。径潮动力非线性相互作用研究有利于揭示河口潮波传播的动力学机制,对河口区水资源高效开发利用具有重要指导意义。本文基于2007—2009年长江河口沿程天生港、江阴、镇江、南京、马鞍山、芜湖的逐日高、低潮位数据及大通站日均流量数据,统计分析不同河段潮波衰减率与余水位坡度随流量的变化特征,结果表明潮波衰减率绝对值与余水位坡度随流量增大并不是单调递增,而是存在一个阈值流量和区域,对应潮波衰减效应的极大值。为揭示这一阈值现象,采用一维水动力解析模型对研究河段的潮波传播过程进行模拟。结果表明,潮波传播的阈值现象主要是由于洪季上游回水作用随流量加强,余水位及水深增大,导致河口辐聚程度减小,而余水位坡度为适应河口形状变化亦有所减小,从而形成相对应的阈值流量和区域。  相似文献